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Fat Modifications

To improve application of vegetable oils in food products they may often be chemically or physically modified to change their properties.The main processes are fractionation, hydrogenation and inter_esterification.
 
Fractionation
Many Oils especially Palm Oil is present in the form of a mixture of high melting point fraction and of a liquid low melting point fraction. The purpose of fractionation process is to separate the liquid fraction called “olein” from the crystallised fraction called “stearin”.
The process comprises three steps:
1. Melting of the oil.
2. Selective crystallization in several cooling steps.
3. Separation of the olein from the stearin by filtration.
 
Hydrogenation
Hydrogenation is a fat modification process mainly used on liquid oils like soya, rape, cotton or sunflower to increase their melting properties by reducing their degree of unsaturation.

Hydrogenation is a reaction involving the use of a catalyst, most generally nickel, temperature and the quantity and flow of hydrogen injected, all of which are essential to guarantee
selective hydrogenation.
 
Interesterification
Inter esterification consists in modifying the physical properties of the oil by an interchange of fatty acids between different triglycerides. This is done by use of a catalyst operating at about 100°C and under vacuum.
The objective is to
1. Change the overall melting profile.
2. improve the compatibility.
3. Improve the plasticity.
 
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